One-Dimensional Inclusion Polymerization of Diene and Vinyl Monomers by Using Methyl Cholate as a Host
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چکیده
منابع مشابه
One-pot synthesis of polyrotaxanes via acyclic diene metathesis polymerization of supramolecular monomers.
A one-pot synthesis of polyrotaxanes has been developed. The method employs a supramolecular monomer comprising a polymerizable ammonium salt and crown ether, in combination with dynamic ADMet polymerization. Ultimately, highly efficient complexation, polymerization, and end-capping were accomplished in a single operation to yield polyrotaxanes with M(w) up to 19.3 kDa and >80% of the repeat un...
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متن کاملAnionic Vinyl Polymerization
The concept of anionic polymerization was first developed by Ziegler and Schlenk in early 1910. Their pioneering work on the polymerization of diene initiated with sodium metal set the stage for the use of alkali metal containing aromatic hydrocarbon complexes as initiators for various α-olefins. In 1939, Scott and coworkers used for the first time the alkali metal complexes of aromatic hydroca...
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ژورنال
عنوان ژورنال: Polymer Journal
سال: 1993
ISSN: 0032-3896,1349-0540
DOI: 10.1295/polymj.25.731